Ibm Dell

September 22nd, 2002

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The choice of electrolite requirements-Liquid electrolyte

Liquid electrolyte

Lithium-ion battery system for the organic electrolyte should first meet the following conditions:

① high lithium ion conductivity in a wide temperature - transport within the electrical conductivity in 3X10-3 ~ 2X10-2 S / cm

② thermal stability, in a wide range of decomposition does not occur;

③ wide electrochemical window, that is stable within a wide voltage range (for lithium-ion batteries, in order to stabilize to 4.5 V>;

④ high chemical stability, that the electrode materials and battery systems, Thinkpad T61 battery(14 inch) such as cathode, anode, collector body, diaphragm, adhesives, etc. Basically, do not react;

⑤ in a wide temperature range for the liquid, the general hope that the temperature range for a 40? 70 degrees;

⑥ on ion solvation has a good performance;

⑦ not toxic, steam down, use of safety;

⑧ reversible electrode reaction as far as possible the conduct of the promotion;

⑨ lithium-ion battery for the goods, the preparation is easy, low cost is also an important consideration.

However, in the above-mentioned factors, the most important factor is safety, long-term stability and reaction rate. Electroluminescent

Liquid solution by the organic solvent and lithium salt electrolyte composed of two parts. XPS M1330 battery Therefore, these factors should be from three to look at: the organic solvent, lithium salt electrolyte and composition of the electrolyte.

For organic solvents, the main is to investigate the flash point, volatility, toxicity and abuse of state of the same below the battery in response to other issues such as battery materials. As the lithium-ion battery with high voltage (typically 4 ~ 4.5 V) also requires the electrolyte should have sufficient oxidation stability. For stability, the main activity is not with the battery electrode materials or can react with the electrode surface forming a layer of ions of a very good film, which requires high ion the mobility and the role of coordination can occur solvent complex formation, so that the number of lithium ion migration is less than 0.5. Therefore, Satellite A100 battery decreasing the polarization effect of lithium ion transference number of lithium ion and increase the conductivity of the electrolyte solvent is an important criterion for selection.

Lithium-ion batteries commonly used in terms of lithium salt electrolyte, including thermal stability, electrochemical stability, high ionic conductivity, low price, easy preparation, less environmental pollution and other factors.

Composition of electrolyte, the major is to investigate the organic electrolyte and electrode compatibility. For the first time in the process of charging the battery, lithium ion battery electrode surfaces to generate a layer of interface membrane (SET), SET membrane formation on the one hand the limited consumption of lithium-ion battery, on the other hand increase the electrode / electrolyte interface resistance, resulting in some hysteresis. But the good SET membrane insoluble organic solvents, allowing relatively free access to lithium-ion electrode and the solvent molecules can not pass through, thereby preventing the solvent molecules were embedded into the electrode and the total damage, improve the electrolyte components at the electrode / electrolyte interface stability. Of course, the organic electrolyte with high conductivity, wide electrochemical window, and good chemical stability of the electrolyte is also required.

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